José Alencar (2003–2007)
Roberto Rodrigues (2003–2006) • Luis Carlos Guedes Pinto (2006–2007)
Olívio Dutra (2003–2005) • Márcio Fortes de Almeida (2005–2007)
Miro Teixeira (2003–2004) • Eunício Oliveira (2004–2005) • Hélio Costa (2005–2007)
Gilberto Gil (2003–2007)
José Viegas Filho (2003–2004) • José Alencar (2004–2006) • Waldir Pires (2006–2007)
Miguel Rossetto (2003–2007)
Luiz Fernando Furlan (2003–2007)
Patrus Ananias (2004–2007)
Cristovam Buarque (2003–2004) • Tarso Genro (2004–2005) • Fernando Haddad (2005–2007)
Agnelo Queiroz (2003–2006) • Francisco Gil Castello Branco (interino) (2003) • Orlando Silva (2006–2007)
Antonio Palocci (2003–2006) • Guido Mantega (2006–2007)
Ciro Gomes (2003–2006) • Pedro Brito (2006–2007)
Marina Silva (2003–2007) • Cláudio Langone (interino) (2003)
Dilma Rousseff (2003–2005) • Mauricio Tolmasquim (2005) • Silas Rondeau (2005–2007)
José Fritsch (2003–2006) • Altemir Gregolin (2006–2007)
Guido Mantega (2003–2004) • Nelson Machado (2004–2005) • Paulo Bernardo (2005–2007)
Ricardo Berzoini (2003–2004) • Amir Lando (2004–2005) • Romero Jucá (2005) • Nelson Machado (2005–2007)
Celso Amorim (2003–2007)
Luiz Gushiken (2003–2005) • Luiz Tadeu Rigo (2005–2007)
Nilmário Miranda (2003–2005) • Mário Mamede Filho (2005–2007) • Paulo Vannuchi (2005–2010)
Matilde Ribeiro (2003–2007)
Emília Fernandes (2003–2004) Nilcea Freire (2004–2007)
Secretaria criada em 2007
Luiz Dulci (2003–2007)
Álvaro Augusto Ribeiro Costa (2003–2007)
Henrique Meirelles (2003–2007)
José Dirceu (2003–2005) • Dilma Rousseff (2005–2007)
Waldir Pires (2003–2006) • Jorge Hage (2003–2006)
Jorge Armando Felix (2003–2007)